A. P. Wight and M. E. Davis, Design and Preparation of Organic???Inorganic Hybrid Catalysts, Chemical Reviews, vol.102, issue.10, pp.3589-3614, 2002.
DOI : 10.1021/cr010334m

Z. Ahmad and J. E. Mark, Biomimetic materials: recent developments in organic-inorganic hybrids, Materials Science and Engineering: C, vol.6, issue.2-3, pp.183-196, 1998.
DOI : 10.1016/S0928-4931(98)00044-7

S. V. Dorozhkin and M. Epple, Biological and Medical Significance of Calcium Phosphates, Angewandte Chemie International Edition, vol.106, issue.311, pp.3130-3146, 2002.
DOI : 10.1007/978-3-642-59762-6

M. F. Ashby and Y. J. Bréchet, Designing hybrid materials, Acta Materialia, vol.51, issue.19, pp.5801-5821, 2003.
DOI : 10.1016/S1359-6454(03)00441-5

L. Nicole, L. Rozes, and C. Sanchez, Integrative Approaches to Hybrid Multifunctional Materials: From Multidisciplinary Research to Applied Technologies, Advanced Materials, vol.303, issue.45, pp.3208-3214, 2012.
DOI : 10.1126/science.1092740

K. E. Lee, N. Morad, T. T. Teng, and B. T. Poh, Development, characterization and the application of hybrid materials in coagulation/flocculation of wastewater: A review, Chemical Engineering Journal, vol.203, pp.370-386, 2012.
DOI : 10.1016/j.cej.2012.06.109

A. Solhy, W. Amer, M. Karkouri, R. Tahir, A. Bouari et al., Bi-functional modified-phosphate catalyzed the synthesis of ??-?????-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating, Journal of Molecular Catalysis A: Chemical, vol.336, issue.1-2, pp.8-15, 2011.
DOI : 10.1016/j.molcata.2010.11.032

P. Becker, Phosphates and phosphoric acid: raw materials technology and economics of the wet process, Fertilizer Science and Technology Series, p.6, 1989.

L. L. Hench, Bioceramics, Journal of the American Ceramic Society, vol.3, issue.1, pp.1705-1728, 1998.
DOI : 10.1056/NEJM199102283240901

F. C. Driessens, M. G. Boltong, O. Bermu-dez, J. A. Planell, M. P. Ginebra et al., Effective formulations for the preparation of calcium phosphate bone cements, Journal of Materials Science: Materials in Medicine, vol.124, issue.3, pp.164-170, 1994.
DOI : 10.6028/jres.078A.043

M. Komath, Development of a fully injectable calcium phosphate cement for orthopedic and dental applications, Bulletin of Materials Science, vol.27, issue.Suppl. 2, pp.415-422, 2003.
DOI : 10.1007/BF02711186

A. K. Cherian, A. C. Rana, S. K. Jain, and D. Dev, Self-Assembled Carbohydrate-Stabilized Ceramic Nanoparticles for the Parenteral Delivery of Insulin, Drug Development and Industrial Pharmacy, vol.11, issue.404, pp.459-463, 2000.
DOI : 10.1021/j100345a006

S. Patil, S. S. Pancholi, S. Agrawal, and G. P. , Surface-Modified Mesoporous Ceramics as Delivery Vehicle for Haemoglobin, Drug Delivery, vol.54, issue.2, pp.193-199, 2004.
DOI : 10.1016/0005-2736(86)90553-5

I. Roy, S. Mitra, A. Maitra, and S. Mozumdar, Calcium phosphate nanoparticles as novel non-viral vectors for targeted gene delivery, International Journal of Pharmaceutics, vol.250, issue.1, pp.25-33, 2003.
DOI : 10.1016/S0378-5173(02)00452-0

Q. Hu, B. Q. Li, M. Wang, and J. C. Shen, Preparation and characterization of biodegradable chitosan/hydroxyapatite nanocomposite rods via in situ hybridization: a potential material as internal fixation of bone fracture, Biomaterials, vol.25, issue.5, pp.779-785, 2004.
DOI : 10.1016/S0142-9612(03)00582-9

A. P. Marques and R. L. Reis, Hydroxyapatite reinforcement of different starch-based polymers affects osteoblast-like cells adhesion/spreading and proliferation, Materials Science and Engineering: C, vol.25, issue.2, pp.215-229, 2005.
DOI : 10.1016/j.msec.2005.01.013

S. N. Pawar and K. J. Edgar, Alginate derivatization: A review of chemistry, properties and applications, Biomaterials, vol.33, issue.11, pp.3279-3305, 2012.
DOI : 10.1016/j.biomaterials.2012.01.007

A. Haug and O. Smidsrod, Selectivity of Some Anionic Polymers for Divalent Metal Ions., Acta Chemica Scandinavica, vol.24, pp.843-854, 1970.
DOI : 10.3891/acta.chem.scand.24-0843

E. Torres, Y. N. Mata, M. L. Blazquez, J. A. Munoz, F. Gonzalez et al., Gold and Silver Uptake and Nanoprecipitation on Calcium Alginate Beads, Langmuir, vol.21, issue.17, pp.7951-7958, 2005.
DOI : 10.1021/la046852k

M. Rajkumar, N. Meenakshisundaram, and V. Rajendran, Development of nanocomposites based on hydroxyapatite/sodium alginate: Synthesis and characterisation, Materials Characterization, vol.62, issue.5, pp.469-479, 2011.
DOI : 10.1016/j.matchar.2011.02.008

G. Vereecke and J. Lemaître, Calculation of the solubility diagrams in the system Ca(OH)2-H3PO4-KOH-HNO3-CO2-H2O, Journal of Crystal Growth, vol.104, issue.4, pp.820-832, 1990.
DOI : 10.1016/0022-0248(90)90108-W

A. H. Roufosse, W. J. Landis, W. K. Sabine, and M. J. Glimcher, Identification of brushite in newly deposited bone mineral from embryonic chicks, Journal of Ultrastructure Research, vol.68, issue.3, pp.235-255, 1979.
DOI : 10.1016/S0022-5320(79)90157-6

M. J. Glimcher, L. C. Bonar, M. D. Grynpas, W. J. Landis, A. H. Roufosse et al., Recent studies of bone mineral: Is the amorphous calcium phosphate theory valid?, Journal of Crystal Growth, vol.53, issue.1, pp.100-119, 1981.
DOI : 10.1016/0022-0248(81)90058-0

P. D. St-pierre, The Preparation of Dicalcium Phosphate Dihydrate and Calcium Pyrophosphate, Journal of the American Chemical Society, vol.77, issue.8, pp.2197-2198, 1955.
DOI : 10.1021/ja01613a050

Y. Tokuoka, Y. Ito, K. Kitahara, Y. Niikura, A. Ochiai et al., ) with Hexagonally Packed Mesoporous Structure by a Sol???Gel Method Using Cationic Surfactant Aggregates as a Template, Chemistry Letters, vol.35, issue.11, pp.1220-1221, 2006.
DOI : 10.1246/cl.2006.1220

G. Thomas and H. Dehbi, Effect of water on monetite synthesis in the solid state, Materials Chemistry and Physics, vol.15, issue.1, pp.1-13, 1986.
DOI : 10.1016/0254-0584(86)90084-2

R. I. Martin and P. W. Brown, Effects of sodium fluoride, potassium fluoride and ammonium fluoride solutions on the hydrolysis of CaHPO4 at 37.4??C, Journal of Crystal Growth, vol.183, issue.3, pp.417-426, 1998.
DOI : 10.1016/S0022-0248(97)00420-X

Y. Fujishiro, H. Yabuki, K. Kawamura, T. Sato, and A. Okuwaki, Preparation of needle-like hydroxyapatite by homogeneous precipitation under hydrothermal conditions, Journal of Chemical Technology & Biotechnology, vol.81, issue.4, pp.349-353, 1993.
DOI : 10.6028/jres.081A.017

H. Lim, A. Kassim, N. Huang, R. Hashim, S. Radiman et al., Fabrication and characterization of 1D brushite nanomaterials via sucrose ester reverse microemulsion, Ceramics International, vol.35, issue.7, pp.2891-2897, 2009.
DOI : 10.1016/j.ceramint.2009.03.044

URL : http://psasir.upm.edu.my/14686/1/Fabrication%20and%20characterization%20of%201D%20brushite%20nanomaterials%20via%20sucrose%20ester%20reverse%20microemulsion.pdf

D. Mohn, N. Doebelin, S. Tadier, R. E. Bernabei, N. A. Luechinger et al., Reactivity of calcium phosphate nanoparticles prepared by flame spray synthesis as precursors for calcium phosphate cements, Journal of Materials Chemistry, vol.10, issue.36, pp.13963-13972, 2011.
DOI : 10.1007/BF03027322

Z. Zou, X. Liu, L. Chen, K. Lin, and J. Chang, Dental enamel-like hydroxyapatite transformed directly from monetite, Journal of Materials Chemistry, vol.235, issue.42, pp.22637-22641, 2012.
DOI : 10.1016/S0022-0248(01)01771-7

D. Lee and P. N. Kumta, Chemical synthesis and stabilization of magnesium substituted brushite, Materials Science and Engineering: C, vol.30, issue.7, pp.934-943, 2010.
DOI : 10.1016/j.msec.2010.04.007

J. Gomez-morales, J. M. Lopez, M. Iafisco, A. Hernandez-hernandez, and M. Prat, Amino Acidic Control of Calcium Phosphate Precipitation by Using the Vapor Diffusion Method in Microdroplets, Crystal Growth & Design, vol.11, issue.11, pp.4802-4809, 2011.
DOI : 10.1021/cg2004547

C. C. Ribeiro, C. C. Barrias, and M. A. Barbosa, Calcium phosphate-alginate microspheres as enzyme delivery matrices, Biomaterials, vol.25, issue.18, pp.4363-4373, 2004.
DOI : 10.1016/j.biomaterials.2003.11.028

S. Teng, J. Shi, B. Peng, and L. Chen, The effect of alginate addition on the structure and morphology of hydroxyapatite/gelatin nanocomposites, Composites Science and Technology, vol.66, issue.11-12, pp.1532-1538, 2006.
DOI : 10.1016/j.compscitech.2005.11.021

R. Stulajterova and L. Medvecky, Effect of calcium ions on transformation brushite to hydroxyapatite in aqueous solutions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.316, issue.1-3, pp.104-109, 2008.
DOI : 10.1016/j.colsurfa.2007.08.036

A. Shkilnyy, J. Brandt, A. Mantion, O. Paris, H. Schlaad et al., Calcium Phosphate with a Channel-like Morphology by Polymer Templating, Chemistry of Materials, vol.21, issue.8, pp.1572-1578, 2009.
DOI : 10.1021/cm803244z

S. Mandel and A. C. Tas, Brushite (CaHPO4??2H2O) to octacalcium phosphate (Ca8(HPO4)2(PO4)4??5H2O) transformation in DMEM solutions at 36.5??C, Materials Science and Engineering: C, vol.30, issue.2, pp.245-254, 2010.
DOI : 10.1016/j.msec.2009.10.009

Q. Ruan, Y. Zhu, Y. Zeng, H. Qian, J. Xiao et al., Ultrasonic-Irradiation-Assisted Oriented Assembly of Ordered Monetite Nanosheets Stacking, The Journal of Physical Chemistry B, vol.113, issue.4, pp.1100-1106, 2009.
DOI : 10.1021/jp809494f

M. Cusack and A. Freer, Biomineralization: Elemental and Organic Influence in Carbonate Systems, Chemical Reviews, vol.108, issue.11, pp.4433-4454, 2008.
DOI : 10.1021/cr078270o

L. R. Frost and J. Sara, Thermal stability of the ???cave??? mineral brushite CaHPO4??2H2O ??? Mechanism of formation and decomposition, Thermochimica Acta, vol.521, issue.1-2, pp.14-17, 2011.
DOI : 10.1016/j.tca.2011.03.035

H. Monma and T. Kamiya, Preparation of hydroxyapatite by the hydrolysis of brushite, Journal of Materials Science, vol.165, issue.12, pp.4247-4250, 1987.
DOI : 10.1007/BF01132015

I. Braccini and S. Perez, -Induced Gelation in Alginates and Pectins:?? The Egg-Box Model Revisited, Biomacromolecules, vol.2, issue.4, pp.1089-1096, 2001.
DOI : 10.1021/bm010008g

URL : https://hal.archives-ouvertes.fr/in2p3-00322981

P. Sikorski, F. Mo, G. Skjak-braek, and B. T. Stokke, Evidence for Egg-Box-Compatible Interactions in Calcium???Alginate Gels from Fiber X-ray Diffraction, Biomacromolecules, vol.8, issue.7, pp.2098-2103, 2007.
DOI : 10.1021/bm0701503