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                <term xml:lang="en">DIFFUSION</term>
                <term xml:lang="en">T-2 RELAXATION TIME</term>
                <term xml:lang="en">POROSITY</term>
                <term xml:lang="en">AMYLOSE</term>
                <term xml:lang="en">CELL WALLS</term>
                <term xml:lang="en">NMR</term>
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                <term xml:lang="en">TEMPS DE RELAXATION</term>
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                <term xml:lang="fr">RMN</term>
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              <p>Various NMR techniques have been used to characterize plant biopolymers, isolated or in interaction with other macromolecules in complex composites. In our investigations, 1 Hand 13 C NMR spectroscopy is used to study, at the molecular scale, complex biochemical processes as those involved during fruit ripening. NMR informs also about the fine structure of biopolymers, about their polymorphism and their crystallinity. At supramolecular scales, measurements of self-diffusion coefficients complement the low-field relaxometry approaches in order to estimate pore sizes in composite systems of biopolymers.</p>
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              <p>Différentes techniques de RMN ont été utilisées pour caractériser des biopolymères d'origine végétale, isolés ou en interaction avec d'autres macromolécules, au sein de composites complexes. Dans nos études, la spectroscopie de RMN 1H et 13C permet de suivre à l'échelle moléculaire des phénomènes biochimiques complexes, comme ceux liés à la maturation des fruits charnus. Elle apporte également des informations sur la structure fine des biopolymères, sur leur polymorphisme et sur leur cristallinité. Aux échelles supramoléculaires, les techniques de mesures de coefficients d'auto-diffusion viennent en complément des mesures de relaxométrie à bas champ pour évaluer la porosité de systèmes complexes à base de biopolymères.</p>
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