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Remarkable selectivity in addition of alcohols to epoxydienes of 5,7 bicyclic and 5,7,6 tricyclic systems
Abstract : (Chemical Equation Presented) Acid-catalyzed addition of alcohols to tricyclic dienyl epoxides such as 4 or bicyclic vinyl oxiranes such as 17 exclusively occurred at the vinyl terminus of unsaturated system through a typical SN2' process affording 1,6- and 1,4-dioxygenated derivatives, respectively.
Mots-clés :
EPOXYDIENES
https://hal-polytechnique.archives-ouvertes.fr/hal-00954807
Déposant : Denis Roura <>
Soumis le : lundi 24 mars 2014 - 17:00:36
Dernière modification le : dimanche 31 mai 2020 - 20:47:35
Déposant : Denis Roura <>
Soumis le : lundi 24 mars 2014 - 17:00:36
Dernière modification le : dimanche 31 mai 2020 - 20:47:35
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