Technical and economical assessment of formic acid to recycle phosphorus from pig slurry by a combined acidification-precipitation process - INRAE - Institut national de recherche pour l’agriculture, l’alimentation et l’environnement Accéder directement au contenu
Article Dans Une Revue Journal of Hazardous Materials Année : 2010

Technical and economical assessment of formic acid to recycle phosphorus from pig slurry by a combined acidification-precipitation process

Evaluation technico-économique de l'utilisation de l'acide formique pour le recyclage du phosphore des lisiers de porcs par un procédé combinant une étape d'acidification et de précipitation

Résumé

Dissolution by acidification followed by a liquid/solid separation and precipitation of phosphorus from the liquid phase is one possibility to recycle phosphorus from livestock effluents. To avoid increase of effluent salinity by using mineral acids in the recycling process, the efficiency of two organic acids, formic and acetic acid, in dissolving the mineral phosphorus from piggery wastewater was compared. The amount of formic acid needed to dissolve the phosphorus was reduced three fold, compared to acetic acid. The amount of magnesium oxide needed for further precipitation was decreased by two with formic acid. Neither the carbon load nor the effluent salinity was significantly increased by using formic acid. An economical comparison was performed for the chemical recycling process (mineral fertilizer) vs. centrifugation (organic fertilizer) considering the centrifugation and the mineral fertilizers sold in the market. After optimisation of the process, the product could be economically competitive with mineral fertilizer as superphosphate in less than 10 years.

Dates et versions

hal-02593541 , version 1 (15-05-2020)

Identifiants

Citer

M.L. Daumer, S. Picard, P. Saint Cast, P. Dabert. Technical and economical assessment of formic acid to recycle phosphorus from pig slurry by a combined acidification-precipitation process. Journal of Hazardous Materials, 2010, 180 (1-3), pp.361-365. ⟨10.1016/j.jhazmat.2010.04.039⟩. ⟨hal-02593541⟩

Collections

IRSTEA INRAE
21 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More