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Novel chiral molecular tweezer from (+)-usnic acid.

Abstract : A new chiral molecular tweezer was synthesized with (1R,2R)-1,2-diaminocyclohexane as spacer and two molecules of (+)-usnic acid as pincers. The ability of this molecular tweezer to bind 2,4,7-trinitrofluorenone was studied. A charge-transfer complex was formed in which TNF was sandwiched between the two usnic acid units with pi-pi-stacked aromatic interactions.
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Submitted on : Friday, June 29, 2012 - 5:02:54 PM
Last modification on : Wednesday, March 30, 2022 - 4:42:53 PM



Béatrice Legouin, Philippe Uriac, Sophie Tomasi, Loic Toupet, Arnaud Bondon, et al.. Novel chiral molecular tweezer from (+)-usnic acid.. Organic Letters, American Chemical Society, 2009, 11 (3), pp.745-748. ⟨10.1021/ol802842m⟩. ⟨inserm-00713269⟩



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