Production of styrene by dehydrogenation of ethylbenzene on a [Re, W]/γ-Al2O3 (K, Ce)/α-Al2O3 porous ceramic catalytic converter - INRAE - Institut national de recherche pour l’agriculture, l’alimentation et l’environnement
Article Dans Une Revue Chemical Engineering and Processing: Process Intensification Année : 2021

Production of styrene by dehydrogenation of ethylbenzene on a [Re, W]/γ-Al2O3 (K, Ce)/α-Al2O3 porous ceramic catalytic converter

Résumé

This paper presents the results of a study on the particularities of the process of dehydrogenation of ethylbenzene to styrene over an original [Re,W]/gamma-Al2O3 (K, Ce)/alpha-Al2O3 porous ceramic catalytic converter, obtained by self-propagating high-temperature synthesis and the sol-gel method. It was found that, over this converter, the output of styrene, with a similar to 100 % selectivity to liquid products, is similar to 23 times higher than that over the same conventional bulk of industrial catalysts. Further, after 6 h of reaction, the degree of carbonization of the converter does not exceed 5 wt.%.
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hal-04009237 , version 1 (20-10-2023)

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А.S. Fedotov, V.I. Uvarov, M.V. Tsodikov, S. Paul, P. Simon, et al.. Production of styrene by dehydrogenation of ethylbenzene on a [Re, W]/γ-Al2O3 (K, Ce)/α-Al2O3 porous ceramic catalytic converter. Chemical Engineering and Processing: Process Intensification, 2021, 160, pp.108265. ⟨10.1016/j.cep.2020.108265⟩. ⟨hal-04009237⟩
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