Behavior of two phenyl urea herbicides in clayey soils and effect of alternating dry-wet conditions on their availability - INRAE - Institut national de recherche pour l’agriculture, l’alimentation et l’environnement Accéder directement au contenu
Article Dans Une Revue Journal of Environmental Science and Health, Part B Année : 2006

Behavior of two phenyl urea herbicides in clayey soils and effect of alternating dry-wet conditions on their availability

Résumé

Adsorption and mobility of linuron (3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea) and diuron (3-(3,4-dichlorophenyl)-1, 1-dimethylurea) were studied in clayey soils from the Gharb area (Morocco). Soils A and B were planted with sun flower (Helianthus annuus) while soil C was planted with sugar cane (Saccharum offcinarum). Adsorption was studied for linuron in soils A and B, while mobility was studied only in soil B. Adsorption data were found to fit the Freundlich equation with correlation coefficients r(2) > 0.9. Freundlich coefficients (K-f, n(f)) were in agreement with L and S isotherm types for soils A and B, respectively. Values of K-oc (195 and 102) indicate moderate adsorption. Desorption isotherms for linuron showed hysteresis for both soils. The pesticide would be more bound to soil A (H = 8.44) than to soil B (H = 4.01). The effect of alternating wet and dry conditions was tested for soils A and B. Results showed that retention would increase in soil subject to an additional wet and dry cycle. In the case of diuron isotherm was of type L in soil C. Desorption was noticeable at high concentrations and tended to decrease when concentrations diminished. Mobility of linuron was tested in polyvinyle chloride (PVC) columns, which received different treatments before their percolation. The pesticide was more mobile in a previously saturated column. In columns subject to a drying step after saturation with water, linuron mobility was greatly reduced.
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Dates et versions

hal-02661564 , version 1 (30-05-2020)

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Jamila Harouari, Abdelmalek Dahchour, Arancha Peña-Heras, Xavier Louchart, Berndt Lennartz, et al.. Behavior of two phenyl urea herbicides in clayey soils and effect of alternating dry-wet conditions on their availability. Journal of Environmental Science and Health, Part B, 2006, 41 (6), pp.883 - 893. ⟨10.1080/03601230600805980⟩. ⟨hal-02661564⟩
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