An experiment has been carried out in Rennes (Brittany, West of France) in June 2000 to estimate atrazine and alachlor volatilisation fluxes after application over a maize crop. Fluxes were calculated using the classical aerodynamic micrometeorological method from vertical gradients of pesticide concentrations, temperature and wind speed. Volatilisation fluxes showed a diurnal pattern of the order of few ng/m2/s for atrazine and the order of a few 10 ng/m2/s for alachlor, leading to cumulated losses of approximately 0.1% of the theoretical application dose for atrazine and several-fold of that in the case of alachlor.