Kinetic study of CO2 hydrate formation based on heat transfer measurement - INRAE - Institut national de recherche pour l’agriculture, l’alimentation et l’environnement Accéder directement au contenu
Communication Dans Un Congrès Année : 2021

Kinetic study of CO2 hydrate formation based on heat transfer measurement

Résumé

Carbon dioxyde hydrates are ice-like crystalline solids composed of CO2 molecules trapped inside cages of hydrogen-bonded water molecules. CO2 hydrates slurries can be used as phase change material for industrial issues of cold distribution, due to high dissociation enthalpy of CO2 hydrate (around 374 kJ kg-1 , higher than that of ice-333 kJ kg-1). However, formation rate of CO2 hydrate is a real limitation, and the way to control and promote it is a key parameter. The present work investigates kinetics studies of CO2 hydrate crystallization for various pressure and stirring rate conditions in a stirred batch jacketed reactor. A heat transfer measurement method is used to determine the rate of hydrate formation. In a first time, the method has been validated by evaluating ice crystallization then it was applied to CO2 hydrates crystallization. Finally, an empirical model have been tested for describing the experimental results and compare to other kinetics determination.
Fichier principal
Vignette du fichier
IIR_PCM2021_1961_Déposé HAL.pdf (1001.23 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Licence : CC BY NC ND - Paternité - Pas d'utilisation commerciale - Pas de modification

Dates et versions

hal-04222125 , version 1 (28-09-2023)

Identifiants

Citer

Véronique Osswald, Pascal Clain, Didier Dalmazzone, Anthony Delahaye, Laurence Fournaison. Kinetic study of CO2 hydrate formation based on heat transfer measurement. 13th IIR Conference on Phase-Change Materials and Slurries for Refrigeration and Air Conditioning, IIR, Sep 2021, Venise (Virtual conference), France. ⟨10.18462/iir.PCM.2021.1961⟩. ⟨hal-04222125⟩
4 Consultations
10 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More