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Photoinduced fragmentation of gas-phase protonated leucine-enkephalin peptide in the VUV range

Abstract : In this article we report new results for action spectroscopy of protonated peptide Leucine enkephalin (YGGFL). By coupling a linear ion trap mass spectrometer with a vacuum ultraviolet (VUV) synchrotron radiation beamline, we investigate photofragmentation pattern of this peptide, through the analysis of tandem mass spectra recorded over a range of VUV photon energies, below and above the ionization energy. The obtained fragmentation patterns are discussed and compared to previous results.
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M. Lj Rankovic, Francis Canon, L. Nahon, Alexandre Giuliani, A. R. Milosavljevic. Photoinduced fragmentation of gas-phase protonated leucine-enkephalin peptide in the VUV range. 29.International Conference on Photonic, Electronic, and Atomic Collisions, Universidad Autónoma de Madrid. ESP., Jul 2015, Tolède, Spain. pp.6, ⟨10.1088/1742-6596/635/1/012034⟩. ⟨hal-02740171⟩

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