Article Dans Une Revue Journal of Cereal Science Année : 2001

Microscopical Study of the Destructuring of Waxy Maize and Smooth Pea Starches by Shear and Heat at Low Hydration

Etude par microscopie de la déstructuration des amidons de maïs cireux et de pois sous cisaillement et chaleur à faible hydratation

Résumé

Smooth pea and waxy maize starches were processed under controlled temperature (<160 °C) conditions at low moisture content (30%) using a rheometer with pre-shearing, to simulate extrusion. Specific mechanical energy was measured and remained lower than 10 3 J/g. Starch modification was analysed at different structural levels by differential scanning calorimetry (DSC), X-ray diffractometry, light microscopy and at the granular level by transmission electron microscopy (TEM). Thermal inputs induced crystallite melting and internal disorganisation of granular structure, whereas mechanical input (SME>10 2 J/g) induced granule fragmentation. Under shearing and heating, the concomitant destructuring mechanisms led to a higher rate of modification. Fragmentation itself induced only partial loss of crystallinity (<50%). Small fragments finally melted due to a local temperature increase contributed by interparticular friction. Susceptibility to fragmentation was related to the mechanical properties of starch granules associated with their architecture and botanical origin.

Dates et versions

hal-04843218 , version 1 (23-01-2025)

Identifiants

Citer

C. Barron, B. Bouchet, G. Della Valle, D.J. Gallant, V. Planchot. Microscopical Study of the Destructuring of Waxy Maize and Smooth Pea Starches by Shear and Heat at Low Hydration. Journal of Cereal Science, 2001, 33 (3), pp.289-300. ⟨10.1006/jcrs.2000.0368⟩. ⟨hal-04843218⟩
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