Skip to Main content Skip to Navigation
Journal articles

Partial and Total Solvent-Free Limonene’s Hydrogenation: Metals, Supports, Pressure, and Water Effects

Abstract : Bio-based solvents menthene and menthane were obtained through limonene’s partial and total hydrogenation under various catalytic conditions. Heterogeneous catalysts based on different active metals and supports (carbon, alumina, and silica) were systematically tested for solvent-free total and partial hydrogenation of limonene under high and low hydrogen pressure. Influences of these catalysts on the formation of menthene, menthane, and cymene, a dehydrogenated product, were determined..The impact of water addition on the conversion and selectivity of the catalysts was also investigated. Amongst all tested catalysts, Rh/Alumina which was never tested for total and partial hydrogenation of limonene was the most effective as 1-menthene was quantitatively produced at low pressure (0.275 MPa) while menthane was mostly obtained at a higher pressure (2.75 MPa). Water addition on Rh/Alumina favoured menthene production even at high pressure. To propose menthane, menthene, and menthane/menthene mixture as an alternative to fossil-based solvents such as n-hexane for the extraction of natural products, β-carotene, vanillin, and rosmarinic acid solubilizations have been investigated. If a modeling approach using COSMO-RS software predicted a comparable solubilization of these 3 compounds for the 3 solvents, experimental assays revealed that menthene solubilizes β-carotene, vanillin, and rosmarinic acid three to five times better than n-hexane.
Complete list of metadata

https://hal.inrae.fr/hal-02881975
Contributor : Line Touloumet <>
Submitted on : Friday, June 26, 2020 - 11:22:02 AM
Last modification on : Tuesday, April 6, 2021 - 4:38:45 PM

Licence


Distributed under a Creative Commons Attribution 4.0 International License

Links full text

Identifiers

Collections

Citation

Fanta Ndongou Moutombi, Anne-Sylvie Fabiano-Tixier, Olivier Clarisse, Farid Chemat, Mohamed Touaibia. Partial and Total Solvent-Free Limonene’s Hydrogenation: Metals, Supports, Pressure, and Water Effects. Journal of Chemistry , Hindawi Publishing Corporation, 2020, 2020, pp.1-11. ⟨10.1155/2020/5946345⟩. ⟨hal-02881975⟩

Share

Metrics

Record views

26